Earth 1

Chemistry from quantum numbers

Atoms

Pick any element. See its nucleus, its shells and every electron's place.

Two lobes of opposite sign, with a flat node through the nucleus.

Brightness is the chance of finding the electron there, |ψ|². Orange: ψ positive. Blue: ψ negative. Drag to turn it.

s-block p-block d-block (transition metals) f-block (lanthanides & actinides)
Bohr shell diagram · electrons drawn on their shells

Element 6

Carbon C

Protons (Z)
6
Neutrons (≈, most common)
6
Electrons
6
Atomic weight
12.011 u
Shells
2 · 4
Block
p-block

Configuration

[He] 2s² 2p²

Full: 1s² 2s² 2p²

Reading it: in 3d⁶, the 3 is the shell n (the energy level), the d is the shape ℓ (s = 0, p = 1, d = 2, f = 3) and the superscript 6 counts the electrons there.

Each shape holds 2(2ℓ + 1) electrons: s 2, p 6, d 10, f 14. Shell n holds 2n² in total. These are the same n, ℓ, m as the hydrogen derivation.

Subshells fill in order of n + ℓ (the Madelung rule), which is why 4s fills before 3d. A few elements, such as Cr, Cu and Au, break the rule because a half-full or full d shell is more stable.

Orbital boxes: one box per m, two electrons per box with opposite spin

↑↓
1s²
↑↓
2s²
↑↑
2p²

Hund’s rule: electrons spread out one per box (same spin) before they pair. Pauli: no two electrons share all four quantum numbers. See the shapes of s, p, d orbitals →